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Designing Organic Syntheses : A Programmed Introduction to the Synthon Approach S. Unit 3 Stereochemistry: Homotopic and heterotopic atoms, prochiral systems chirality, molecules with more than one chiral centre, threo and erythro isomers, optical purity, optical activity in absence of chiral carbon, helical molecules, admantoids, catenanes, Conformational analysis of fused bicyclic, tricyclic and bridged ring systems, effect of conformations on reactivity in acyclic and cyclic compounds, Cram’s and Prelog’s rules, stereospecific and stereoselective reactions. Michael addition, Wittig reaction, Mannich reaction, Stork enamine synthesis, Baylis-Hillman reaction, applications of organometallics: use of Grignard reagent, organo-lithium and –copper-lithium complexes. principles and applications of protective groups in protection of hydroxyl, amino, carbonyl and carboxyl groups, synthetic strategies for cyclic compounds, retrosynthesis and synthetic approaches to some complex molecules such as camphor, longifoline, prostaglandins etc Unit 2 Carbon-carbon bond forming reactions: Knovenagel condensation, Darzon condensation. Organic Chemistry M Sc Semester 3 CHE2320COC (3 Credits) Organic Synthesis &Stereochemistry Unit 1 Organic synthesis: Reterosynthsis, synthons and synthetic equivalents, functional group interconversion, Synthesis of amines, regiospecific, chemospecific and stereospecific reactions, umpolung methods. |
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